CLEAVAGE OF BOTH ALKYL C-H BONDS AND ARYL C-F BONDS AND CONCOMITANT C-C BOND FORMATION IN A PENTAMETHYLCYCLOPENTADIENYLRHODIUM PHOSPHINE COMPLEX - X-RAY STRUCTURE OF [(ETA(5)-C(5)ME(3)[CH2C(6)F(4)P(C6F5)CH2](2)-1,3)RHCL]+BF4-

被引：34

作者：

ATHERTON, MJ

FAWCETT, J

HOLLOWAY, JH

HOPE, EG

KARACAR, A

RUSSELL, DR

SAUNDERS, GC

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,LEICS,ENGLAND

[2] BNFL FLUOROCHEM LTD,PRESTON PR4 0XJ,LANCS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 02期

关键词：

D O I：

10.1039/c39950000191

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction between bis(dipentafluorophenylphosphino)ethane, dfppe, and [{(eta(5)-C(5)Me(5))RhCl(mu-Cl)}(2)] proceeds with cleavage of two C-F bonds and two C-H bonds and formation of two C-C bonds to yield the ionic complex 1a.

引用

页码：191 / 192

页数：2

共 15 条

[1] ACTIVATION OF AROMATIC CARBON FLUORINE BONDS BY ORGANOPLATINUM COMPLEXES [J].

ANDERSON, CM ;

CRESPO, M ;

FERGUSON, G ;

LOUGH, AJ ;

PUDDEPHATT, RJ .

ORGANOMETALLICS, 1992, 11 (03) :1177-1181

[2]

ATHERTON MJ, UNPUB

[3] C-F BOND ACTIVATION BY IRIDIUM(I) - A UNIQUE PROCESS INVOLVING P-C BOND-CLEAVAGE, P-F BOND FORMATION AND NET RETENTION OF OXIDATION-STATE [J].

BLUM, O ;

FROLOW, F ;

MILSTEIN, D .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (04) :258-259

[4] METALATION OF AZOBENZENES BY FLUORINE-ABSTRACTION - STRUCTURE OF A RUTHENIUM COMPLEX CONTAINING NONAFLUORO(PHENYLAZO)PHENYL-2C,N' AND DIPHENYL-2-(ETA-CYCLOPENTADIENYLPHENYL)PHOSPHINE GROUPS [J].

BRUCE, MI ;

GARDNER, RCF ;

GOODALL, BL ;

STONE, FGA ;

DOEDENS, RJ ;

MORELAND, JA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1974, (05) :185-186

[5] OXIDATIVELY INDUCED REDUCTIVE ELIMINATION - A NOVEL TITANIUM COMPLEX RESULTING FROM C-F BOND ACTIVATION [J].

BURK, MJ ;

STALEY, DL ;

TUMAS, W .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (11) :809-810

[6] INTRAMOLECULAR ACTIVATION OF A C-F BOND AT PLATINUM(II) IN THE PRESENCE OF WEAKER C-X BONDS (X = H, CL AND BR) [J].

CRESPO, M ;

MARTINEZ, M ;

SALES, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (11) :822-823

[7] CHELATE BINDING PREFERENCES IN CPML4 COMPLEXES - PREPARATION AND STRUCTURE OF TRANS-(ETA-5-C5H5)MO[(C6F5)2PCH2CH2P(C6F5)2](CO)CL [J].

ERNST, MF ;

RODDICK, DM .

INORGANIC CHEMISTRY, 1990, 29 (18) :3627-3630

[8]

GREENWOOD NN, 1984, CHEM ELEMENTS, P949

[9] RING-METHYL ACTIVATION IN PENTAMETHYLCYCLOPENTADIENYL COMPLEXES .3. SYNTHESIS AND REACTIONS OF (ETA-4-TETRAMETHYLFULVENE)(ETA-5-CYCLOPENTADIENYL)RHODIUM AND IRIDIUM [J].

GUSEV, OV ;

SERGEEV, S ;

SAEZ, IM ;

MAITLIS, PM .

ORGANOMETALLICS, 1994, 13 (05) :2059-2065

[10] SEQUENTIAL ARENE COORDINATION AND C-F INSERTION IN THE REACTIONS OF (ETA-5-PENTAMETHYLCYCLOPENTADIENYL)RHODIUM COMPLEXES WITH HEXAFLUOROBENZENE [J].

JONES, WD ;

PARTRIDGE, MG ;

PERUTZ, RN .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (04) :264-266

← 1 2 →