TRIS(TRIMETHYLSILYL)SILANE AND DIPHENYLSILANE IN THE RADICAL CHAIN DIDEOXYGENATION OF 1,6-ANHYDRO-D-GLUCOSE - A COMPARATIVE-STUDY

被引：22

作者：

BARTON, DHR ^{[1
]}

JANG, DO ^{[1
]}

JASZBERENYI, JC ^{[1
]}

机构：

[1] TEXAS A&M UNIV SYST,DEPT CHEM,COLL STN,TX 77843

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 44期

关键词：

D O I：

10.1016/S0040-4039(00)61003-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 2,4-bis-thionocarbonate 3 of 1,6-anhydro-D-glucose 1 can be transformed to the corresponding dideoxy compounds 5 with diphenylsilane 7 as well as with tris(trimethylsilyl)silane 4 in a radical chain reaction.

引用

页码：6629 / 6632

页数：4

共 46 条

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[5] THE INVENTION OF RADICAL REACTIONS .21. SIMPLE METHODS FOR THE RADICAL DEOXYGENATION OF PRIMARY ALCOHOLS
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[6] AN IMPROVED RADICAL CHAIN PROCEDURE FOR THE DEOXYGENATION OF SECONDARY AND PRIMARY ALCOHOLS USING DIPHENYLSILANE AS HYDROGEN-ATOM DONOR AND TRIETHYLBORANE-AIR AS INITIATOR
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[7] RADICAL DEOXYGENATIONS AND DEHALOGENATIONS WITH DIALKYL PHOSPHITES AS HYDROGEN-ATOM SOURCE
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[J]. TETRAHEDRON LETTERS, 1992, 33 (17) : 2311 - 2314
[8] RADICAL MONODEOXYGENATION AND DIDEOXYGENATION WITH THE TRIETHYLSILANE + BENZOYL PEROXIDE SYSTEM
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[J]. TETRAHEDRON LETTERS, 1991, 32 (49) : 7187 - 7190
[9] BARTON DHR, 1981, SYNTHESIS-STUTTGART, P743
[10] TOWARDS DIDEOXYNUCLEOSIDES - THE SILICON APPROACH
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[J]. TETRAHEDRON LETTERS, 1991, 32 (23) : 2569 - 2572

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