IMINOPHOSPHORANE-MEDIATED ONE-POT CONVERSION OF ALLYL AZIDES INTO ALPHA-ALLYLATED NITRILES BY A CONSECUTIVE STAUDINGER-REACTION/AZA-WITTIG-REACTION/3-AZA-CLAISEN-REARRANGEMENT PROCESS

被引：20

作者：

MOLINA, P

ALAJARIN, M

LOPEZLEONARDO, C

机构：

[1] Departamento de Quimica Organica, Facultad de Ciencias, Universidad de Murcia, 30071 Murcia, Campus de Espinardo

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 32期

关键词：

D O I：

10.1016/0040-4039(91)80623-E

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

One-pot conversion of allyl azides 1 into nitriles 3 under mild and neutral conditions is reported. The method involves sequential treatment of 1 with triphenylphosphine and the corresponding ketene to give 3.

引用

页码：4041 / 4044

页数：4

共 16 条

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