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VIBRATIONAL AND NMR SPECTROSCOPIC STUDIES OF CADMIUM(II) BIS (DIALKYL DITHIOPHOSPHINATES)
被引:18
作者:
CASAS, JS
[1
]
GARCIATASENDE, MS
[1
]
SANCHEZ, A
[1
]
SORDO, J
[1
]
VAZQUEZLOPEZ, EM
[1
]
CASTELLANO, EE
[1
]
ZUKERMANSCHPECTOR, J
[1
]
机构:
[1] UNIV SAO PAULO,INST FIS & QUIM SAO CARLOS,BR-13560 SAO CARLOS,SP,BRAZIL
关键词:
D O I:
10.1016/S0020-1693(00)85134-8
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
The compounds [Cd(S2PR2)2] (R=ethyl and cyclohexyl) have been studied in the solid state by vibrational (IR and Raman) spectroscopy and in solution in CH2Cl2 using molecular weight measurements and IR and NMR (C-13, P-31, Cd-113) spectroscopy. The influence of tributylphosphine on the association of the compounds in solution and on the coordination of the metallic centre has been explored.
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页码:137 / 142
页数:6
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