(Z)-3-HEXENYL-BETA-D-GLUCOPYRANOSIDE IN FRESH TEA LEAVES AS A PRECURSOR OF GREEN ODOR

被引：44

作者：

KOBAYASHI, A

KUBOTA, K

JOKI, Y

WADA, E

WAKABAYASHI, M

机构：

[1] Laboratory of Food Chemistry, Department of Nutrition and Food Science, Ochanomizu University, Tokyo, 2-1-1 Ohtsuka, Bunkyo-ku

来源：

BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY | 1994年 / 58卷 / 03期

关键词：

D O I：

10.1271/bbb.58.592

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The glycoside fraction from fresh tea leaves was acetylated and separated by silica gel column chromatography. A crystalline product was identified as (Z)-3-hexenyl-(tetra-O-acetyl)-beta-D-glucopyranoside from spectrometric data which were identical with those of an authentic synthesized sample in all respects. There are two possible processes for the formation of the greenish odor of plant materials, these being a biosynthetic process from the lipid and enzymatic hydrolysis of (Z)-3-hexenyl-beta-D-glucoside.

引用

页码：592 / 593

页数：2

共 8 条

[1]

FLOWERS HM, 1972, METHODS CARBOHYD CHE, V6, P474

[2] BIOSYNTHESIS OF TRANS-2-HEXENAL IN CHLOROPLASTS FROM THEA-SINENSIS [J].

HATANAKA, A ;

KAJIWARA, T ;

SEKIYA, J .

PHYTOCHEMISTRY, 1976, 15 (07) :1125-1126

[3] SESQUITERPENOIDS AND (Z)-3-HEXENYL GLUCOSIDE FROM PERTYA-GLABRESCENS AND A GLUCOSIDIC SESQUITERPENE FROM PERTYA-SCANDENS [J].

NAGUMO, S ;

KAWAI, K ;

NAGASE, H ;

INOUE, T ;

NAGAI, M .

YAKUGAKU ZASSHI-JOURNAL OF THE PHARMACEUTICAL SOCIETY OF JAPAN, 1984, 104 (12) :1223-1231

[4] VOLATILE AND NONVOLATILE FORMS OF AROMA COMPOUNDS IN TEA LEAVES AND THEIR CHANGES DUE TO INJURY [J].

SAIJO, R ;

TAKEO, T .

AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1973, 37 (06) :1367-1373

[5]

SAIJO R, 1974, PHYTOCHEMISTRY, V14, P181

[6]

Yamanishi T, 1990, FLAVORS OFF FLAVORS, P169

[7] BENZYL GLUCOSIDE FROM TEA LEAVES [J].

YANO, M ;

JOKI, Y ;

MUTOH, H ;

KUBOTA, K ;

KOBAYASHI, A .

AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1991, 55 (04) :1205-1206

[8] STUDIES ON THE PRECURSORS OF MONOTERPENE ALCOHOLS IN TEA LEAVES [J].

YANO, M ;

OKADA, K ;

KUBOTA, K ;

KOBAYASHI, A .

AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1990, 54 (04) :1023-1028

← 1 →