SYNTHESIS AND REACTIVITY OF THE NEW, CHIRAL SILYLPHOSPHITE ESTERS ((+)-O,O-DIMETHYL-L-TARTRATE)POSIR3 (R3=PH3,(T)BUME2,ET3)

被引：12

作者：

PICKERSGILL, IF ^{[1
]}

DEVITT, PG ^{[1
]}

KEE, TP ^{[1
]}

机构：

[1] UNIV LEEDS,SCH CHEM,LEEDS LS2 9JT,W YORKSHIRE,ENGLAND

来源：

SYNTHETIC COMMUNICATIONS | 1993年 / 23卷 / 12期

关键词：

D O I：

10.1080/00397919308011261

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The new, chiral silylphosphite compounds (O,O-dimethyl-L-tartrato)POSiR3 (R3 = Ph3, tBuMe2, Et3) have been synthesised and their activity as asymmetric phosphonylating reagents investigated.

引用

页码：1643 / 1650

页数：8

共 8 条

[1]

Abramov V. S., 1954, DOKL AKAD NAUK SSSR, V95, P991

[2] CONFIGURATIONAL STABILITY IN SOME 3-COORDINATE PHOSPHORUS COMPOUNDS [J].

FONTAL, B ;

GOLDWHIT.H .

TETRAHEDRON, 1966, 22 (10) :3275-&

[3] ASYMMETRIC SILYLPHOSPHITE ESTERS - SYNTHESIS AND REACTIVITY OF (RAC-O,O-BINAPHTHOLATO)POSIR3 (R3=PH3,(T)BUME2,ET3) [J].

GREENE, N ;

KEE, TP .

SYNTHETIC COMMUNICATIONS, 1993, 23 (12) :1651-1657

[4]

HILDEBRAND RL, 1983, ROLE PHOSPHONATES LI

[5] 10-MEMBERED RING HETEROCYCLIC MOLECULES CONTAINING PHOSPHORUS, OXYGEN, AND NITROGEN [J].

ROBERT, JB ;

WEICHMANN, H .

JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (15) :3031-3035

[6] NEW, CHIRAL SILYLATED ORGANOPHOSPHORUS(III) REAGENTS - SYNTHESES AND APPLICATIONS IN THE ASYMMETRIC PHOSPHORYLATION OF ALDEHYDES [J].

SUM, V ;

DAVIES, AJ ;

KEE, TP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (24) :1771-1773

[7] PRACTICAL SYNTHESES OF CHELATING BIS(DIOXAPHOSPHOLANE) LIGANDS THROUGH CHLORODIOXAPHOSPHOLANE INTERMEDIATES AND DEMONSTRATION OF CATALYTIC COMPETENCE OF BIS(PHOSPHITE)RHODIUM CATIONS [J].

WINK, DJ ;

KWOK, TJ ;

YEE, A .

INORGANIC CHEMISTRY, 1990, 29 (24) :5006-5008

[8] SILYL ESTERS OF PHOSPHORUS COMMON INTERMEDIATES IN SYNTHESIS [J].

WOZNIAK, L ;

CHOJNOWSKI, J .

TETRAHEDRON, 1989, 45 (09) :2465-2524

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