CHARACTERIZATION OF SNO2 FILMS DEPOSITED BY DC GAS-DISCHARGE ACTIVATING REACTION EVAPORATION ONTO AMORPHOUS AND CRYSTALLINE SUBSTRATES

被引:18
作者
ZHU, YH
LU, H
LU, YC
PAN, XR
机构
[1] Department of Physics, East China University of Chemical Technology, Shanghai
基金
中国国家自然科学基金;
关键词
D O I
10.1016/0040-6090(93)90462-X
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A d.c. gas discharge activating reaction evaporation technique was used to prepare gas-sensitive SnO2 films. The thin films of ultrafine particles and large-area crystallites were grown successfully on glass and SiO2(110) substrates respectively. The films were characterized by X-ray photoelectron spectroscopy, transmission and scanning electron microscopies and X-ray diffraction, and their gas-sensing properties were also investigated. The ultrafine particle film with average particle size of 40 nm exhibited a high sensitivity of 77 at 210-degrees-C to 100 PPM C2H5OH and a good selectivity for detecting C2H5OH in the presence of gasoline gas; the large-area crystalline thin film exhibited a fast response below 2 s to C2H5OH at 330-degrees-C and a remarkable oscillation of the conductivity after pulse exposure to C2H5OH.
引用
收藏
页码:82 / 86
页数:5
相关论文
共 9 条
[1]  
CHANG SC, 1983, P INT M CHEM SENSORS, P78
[2]   TRANSPARENT CONDUCTORS - A STATUS REVIEW [J].
CHOPRA, KL ;
MAJOR, S ;
PANDYA, DK .
THIN SOLID FILMS, 1983, 102 (01) :1-46
[3]   SINGLE-CRYSTAL METAL-OXIDE GAS SENSORS [J].
GEATCHES, RM ;
CHADWICK, AV ;
WRIGHT, JD .
SENSORS AND ACTUATORS B-CHEMICAL, 1991, 4 (3-4) :467-472
[4]  
KANEFUSA S, 1983, CHEM SENSORS, P84
[5]   THIN-FILMS FOR GAS SENSORS [J].
LALAUZE, R ;
BREUIL, P ;
PIJOLAT, C .
SENSORS AND ACTUATORS B-CHEMICAL, 1991, 3 (03) :175-182
[6]   ELECTRICAL-PROPERTIES OF TIN OXIDE ULTRAFINE PARTICLE FILMS [J].
OGAWA, H ;
ABE, A ;
NISHIKAWA, M ;
HAYAKAWA, S .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1981, 128 (09) :2020-2025
[7]   INFLUENCE OF GAS ATMOSPHERE ON THERMOPOWER MEASUREMENTS IN TIN OXIDE THIN-FILMS [J].
PISARKIEWICZ, T ;
STAPINSKI, T .
THIN SOLID FILMS, 1989, 174 :277-283
[8]   STUDIES OF ULTRAFINE PARTICLES IN JAPAN - CRYSTALLOGRAPHY - METHODS OF PREPARATION AND TECHNOLOGICAL APPLICATIONS [J].
UYEDA, R .
PROGRESS IN MATERIALS SCIENCE, 1991, 35 (01) :1-96