INFLUENCING THE AGGREGATION OF MANGANESE COMPLEXES BY DIFFERENT BASES - FORMATION OF [MN(O2CCF3)2(PY)4] AND [MN3(O2CCF3)6(BENZ)6]

被引：35

作者：

HUBNER, K ^{[1
]}

ROESKY, HW ^{[1
]}

NOLTEMEYER, M ^{[1
]}

BOHRA, R ^{[1
]}

机构：

[1] UNIV GOTTINGEN, INST ANORGAN CHEM, TAMMANNSTR 4, W-3400 GOTTINGEN, GERMANY

来源：

CHEMISCHE BERICHTE-RECUEIL | 1991年 / 124卷 / 03期

关键词：

MANGANESE COMPLEXES; AGGREGATION;

D O I：

10.1002/cber.19911240316

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Manganese powder reacts quantitatively with trifluoroacetic acid to yield Mn(O2CCF3)2 (1). The aggregation of 1 is directed by different N-containing bases. Pyridine (py) forms the mononuclear complex [Mn(O2CCF3)2(py)4] (2), while benzonitrile (benz) yields the trinuclear complex [Mn3(O2CCF3)6(benz)6] (3). The X-ray structures of 2 and 3 are described.

引用

页码：515 / 517

页数：3

共 25 条

[1] AMINE AND AMINE N-OXIDE COMPLEXES OF SOME FIRST-ROW TRANSITION-METAL TRIFLUOROACETATES AND TRICHLOROACETATES [J].

AMASA, S ;

BROWN, DH ;

SHARP, DWA .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (19) :2892-&

[2]

BACOCK GI, 1987, NEW COMPREHENSIVE BI, P125

[3] CRYSTAL-STRUCTURE OF MANGANESE ACETATE TETRAHYDRATE [J].

BERTAUT, EF ;

DUC, TQ ;

BURLET, P ;

THOMAS, M ;

MOREAU, JM .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1974, 30 (SEP15) :2234-2236

[4] EVIDENCE THAT PROTEIN-B OF THE THIOSULFATE-OXIDIZING SYSTEM OF THIOBACILLUS-VERSUTUS CONTAINS A BINUCLEAR MANGANESE CLUSTER [J].

CAMMACK, R ;

CHAPMAN, A ;

LU, WP ;

KARAGOUNI, A ;

KELLY, DP .

FEBS LETTERS, 1989, 253 (1-2) :239-243

[5] CHEMICAL AND PHYSICAL-PROPERTIES OF TRIANGULAR BRIDGED METAL-COMPLEXES [J].

CANNON, RD ;

WHITE, RP .

PROGRESS IN INORGANIC CHEMISTRY, 1988, 36 :195-298

[6] MANGANESE CARBOXYLATE CHEMISTRY AND ITS BIOLOGICAL RELEVANCE [J].

CHRISTOU, G .

ACCOUNTS OF CHEMICAL RESEARCH, 1989, 22 (09) :328-335

[7] THE MANGANESE SITE OF THE PHOTOSYNTHETIC WATER-SPLITTING ENZYME [J].

GEORGE, GN ;

PRINCE, RC ;

CRAMER, SP .

SCIENCE, 1989, 243 (4892) :789-791

[8]

KUZUNOKI M, 1983, OXYGEN EVOLVING SYST, P165

[9]

PECORARO VL, 1988, PHOTOCHEM PHOTOBIOL, V48, P249

[10] SYNTHESIS AND CHARACTERIZATION OF THE LINEAR TRINUCLEAR COMPLEXES [MN-3(2)(O2CCH3)6(BIPHME)2, [FE-3(2)(O2CCH3)6(BIPHME)2] [J].

RARDIN, RL ;

BINO, A ;

POGANIUCH, P ;

TOLMAN, WB ;

LIU, SC ;

LIPPARD, SJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1990, 29 (07) :812-814

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