FORMATION OF A NEW BIS-ORGANOCOPPER REAGENT FROM THE REACTION OF 2,3-DICHLOROPROPENE AND HIGHLY-ACTIVE ZERO VALENT COPPER DERIVED FROM A CUCN.2LICL COMPLEX

被引：8

作者：

STACK, DE ^{[1
]}

RIEKE, RD ^{[1
]}

机构：

[1] UNIV NEBRASKA,DEPT CHEM,LINCOLN,NE 68588

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 44期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(00)60989-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Highly reactive zero valent copper derived from a CuCN.2LiCl complex reacts directly with 2,3-dichloropropene to yield a new bis-organocopper species containing both a nucleophilic allylic and vinylic moiety. This new bis-ogranocopper reagent undergoes selective one-pot addition to two different electrophiles in good to excellent yields.

引用

收藏

页码：6575 / 6578

页数：4

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