SYNTHESIS AND REACTIONS OF TETRACARBONYLMANGANESE COMPLEXES OF BENZOYLSILANES

被引：7

作者：

CAMBIE, RC ^{[1
]}

MUI, LCM ^{[1
]}

RUTLEDGE, PS ^{[1
]}

WOODGATE, PD ^{[1
]}

机构：

[1] UNIV AUCKLAND,DEPT CHEM,AUCKLAND,NEW ZEALAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 464卷 / 02期

关键词：

MANGANESE; CARBONYL; SILANE; ALDEHYDE; ALKENE; ALKYNE;

D O I：

10.1016/0022-328X(94)87271-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of benzoylsilane with benzylpentacarbonylmanganese (1) give ortho-eta(2)-manganese complexes in high yield. The derived aldehyde complex can then be formed by fluoride-catalysed desilylation of the acylsilane complex. Coupling reactions of the acylsilane complexes with alkenes or alkynes are reported.

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收藏

页码：171 / 182

页数：12

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