CIS-TRANS ISOMERIZATION AND ATROPISOMERISM OF OCTAETHYL 1,2-BIS(COPROPORPHYRINYL)ETHYLENE ESTER

被引：21

作者：

PONOMAREV, GV

BOROVKOV, VV

SHULGA, AM

SAKATA, Y

机构：

[1] RITE, KIZU, KYOTO 61902, JAPAN

[2] RUSSIAN MINIST HLTH, INST BIOPHYS, MOSCOW 123182, RUSSIA

[3] BYELARUSSIAN ACAD SCI, INST PHYS, MINSK 2206022, BELARUS

[4] OSAKA UNIV, INST SCI & IND RES, IBARAKI, OSAKA 567, JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 17期

关键词：

D O I：

10.1039/c39940001927

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidation of the ethane-bridged dimer of coproporphyrin-I proceeds stereoselectively to produce only the sterically unhindered trans-ethylene-bridged atropisomer, which undergoes thermal isomerisation to give two atropisomers of the cis-dimer.

引用

页码：1927 / 1928

页数：2

共 10 条

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