SYNTHESIS AND PROPERTIES OF CIS-1,2-BIS(OCTAETHYLPORPHYRINYL)ETHYLENE

被引：72

作者：

PONOMAREV, GV

BOROVKOV, VV

SUGIURA, K

SAKATA, Y

SHULGA, AM

机构：

[1] OSAKA UNIV, INST SCI & IND RES, IBARAKI, OSAKA 567, JAPAN

[2] BYELARUSSIAN ACAD SCI, INST PHYS, MINSK 220602, BELARUS

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 13期

关键词：

PORPHYRIN; PORPHYRIN DIMER; FACE-TO-FACE ORIENTATION;

D O I：

10.1016/S0040-4039(00)60369-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new cis-form of ethylene-bridged octaethylporphyrin dimer 3a has been obtained by isomerization of the corresponding trans-isomer 2a. On the basis of spectral data the structure of 3a was assigned to be close to a ''face-to-face'' orientation. Reflecting the peculiar structure of 3a UV-vis and H-1 NMR spectra are remarkably distinguished from those of ordinary porphyrins.

引用

页码：2153 / 2156

页数：4

共 9 条

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