SURFACE-ENHANCED RAMAN-SCATTERING OF ADSORBATES

被引：182

作者：

OTTO, A

机构：

[1] Oberflächenwissenschaft, Heinrich-Heine-Universität Düsseldorf, Düsseldorf

来源：

JOURNAL OF RAMAN SPECTROSCOPY | 1991年 / 22卷 / 12期

关键词：

D O I：

10.1002/jrs.1250221204

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

This review concentrates on the electronic contribution to surface-enhanced Raman scattering (SERS). This so-called 'chemical effect' is quantitatively separated from classical electromagnetic enhancement. It proceeds by increased electron-photon coupling at an atomically rough surface and by temporary charge transfer to adsorbate orbitals. These concepts are supported by various experimental results. The model accounts for the chemical specificity and vibrational selectivity of SERS and (partly) for the 'SERS specificity' of various metals.

引用

页码：743 / 752

页数：10

共 104 条

[11] NORMAL RAMAN-SCATTERING FROM PYRIDINE ADSORBED ON THE LOW-INDEX FACES OF SILVER
CAMPION, A
MULLINS, DR
[J]. CHEMICAL PHYSICS LETTERS, 1983, 94 (06) : 576 - 579
[12] UNENHANCED RAMAN-SCATTERING FROM PYRIDINE ADSORBED ON STEPPED AND KINKED SILVER SURFACES UNDER ULTRAHIGH-VACUUM
CAMPION, A
MULLINS, DR
[J]. SURFACE SCIENCE, 1985, 158 (1-3) : 263 - 270
[13] Chang R. K., 1982, SURFACE ENHANCED RAM
[14] TEMPORARY ANIONS OF THE FLUOROETHYLENES
CHIU, NS
BURROW, PD
JORDAN, KD
[J]. CHEMICAL PHYSICS LETTERS, 1979, 68 (01) : 121 - 126
[15] DISTANCE DEPENDENCE OF SURFACE-ENHANCED RESONANCE RAMAN ENHANCEMENT IN LANGMUIR-BLODGETT DYE MULTILAYERS
COTTON, TM
UPHAUS, RA
MOBIUS, D
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (23) : 6071 - 6073
[16] CREIGHTON JA, 1988, SPECTROSCOPY SURFACE, V16, pCH2
[17] RESONANCE SCATTERING OF ELECTRONS FROM N-2, CO, O-2, AND H-2 ADSORBED ON A SILVER SURFACE
DEMUTH, JE
SCHMEISSER, D
AVOURIS, P
[J]. PHYSICAL REVIEW LETTERS, 1981, 47 (16) : 1166 - 1169
[18] CH VIBRATION SOFTENING AND DEHYDROGENATION OF HYDROCARBON MOLECULES ON NI(111) AND PT(111)
DEMUTH, JE
IBACH, H
LEHWALD, S
[J]. PHYSICAL REVIEW LETTERS, 1978, 40 (15) : 1044 - 1047
[19] DEVORE TC, 1976, INORG CHEM, V15, P1318, DOI 10.1021/ic50160a014
[20] PI-STAR AND OMEGA-STAR MOLECULAR-ORBITALS OF CONDENSED FILMS OF CHLOROBENZENES AND HEXAFLUOROBENZENE OBSERVED BY INVERSE PHOTOEMISSION
DUDDE, R
REIHL, B
OTTO, A
[J]. JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (06) : 3930 - 3934

← 1 2 3 4 5 6 7 8 9 10 →