SYNTHETIC APPLICATIONS OF GROUP-IV METAL IMIDO COMPLEX-ALKYNE [2+2] CYCLOADDITIONS - A CONCISE TOTAL SYNTHESIS OF (+/-)-MONOMORINE

被引：116

作者：

MCGRANE, PL ^{[1
]}

LIVINGHOUSE, T ^{[1
]}

机构：

[1] MONTANA STATE UNIV,DEPT CHEM & BIOCHEM,BOZEMAN,MT 59717

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 05期

关键词：

D O I：

10.1021/jo00031a003

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Monocyclopentadienyltitanium(IV) imido complexes readily undergo [2 + 2] cycloadditions with representative alkynes at less-than-or-equal-to 25-degrees-C. The present study details the application of a catalytic variation of this reaction in a convergent synthesis of (+/-)-monomorine.

引用

页码：1323 / 1324

页数：2

共 38 条

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