NEW CU-TE CLUSTERS

被引：48

作者：

FENSKE, D

STECK, JC

机构：

[1] Institut Für Anorganische Chemie, Universität Karlsruhe, D-W-7500, Engesserstrasse

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 02期

关键词：

D O I：

10.1002/anie.199302381

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Frank-Kasper polyhedrons suitable for the description of the structures of intermetallic phases can also be used to describe the structures of the Cu-rich clusters, which are among the compounds formed by the reactions of CuCl with phosphanes and Te(Si-Me3)2. The Cu-poor compound 1 in contrast contains a Cu, butterfly cluster with two mu4-Te(2)-2 ligands (structure shown right).

引用

页码：238 / 242

页数：5

共 31 条

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[7] NEW COPPER CLUSTERS CONTAINING SE AND PET3 AS LIGANDS - [CU70SE35(PET3)22] AND [CU20SE13(PET3)12]
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[9] NEW INTERMEDIATE STEPS IN THE SYNTHESIS OF LARGER NICKEL CLUSTERS
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[10] SYNTHESIS AND STRUCTURE OF NOVEL CU-CLUSTERS - [CU30-XSE15(PIPR3)12] (X = 0,1) AND [CU36SE18(PTBU3)12]
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