CATIONIC RHODIUM COMPLEX-CATALYZED HIGHLY SELECTIVE HYDROSILYLATION OF PROPYNYLIC ALCOHOLS - A CONVENIENT SYNTHESIS OF (E)-GAMMA-SILYL ALLYLIC ALCOHOLS

被引：23

作者：

TAKEUCHI, R

NITTA, S

WATANABE, D

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 15期

关键词：

D O I：

10.1039/c39940001777

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cationic rhodium complex-catalysed hydrosilylation of alk-1-ynols including propynylic alcohols with triethylsilane is highly selective to give (E)-1-triethylsilyl alk-1-enols as products in excellent yields.

引用

页码：1777 / 1778

页数：2

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