GENERATION OF ACYL RADICALS FROM 1-OXIDOALKYLIDENECHROMIUM(0) COMPLEXES BY TREATMENT WITH BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)COPPER(II) AND THEIR REACTIONS WITH OLEFINS

被引：14

作者：

SAKURAI, H

NARASAKA, K

机构：

来源：

CHEMISTRY LETTERS | 1994年 / 11期

关键词：

D O I：

10.1246/cl.1994.2017

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetramethylammonium pentacarbonyl(1-oxidoalkylidene)chromium(0) complexes are oxidized with bis(2,2,6,6-tetramethyl-3,5-heptanedionato)copper(II) to generate acyl radicals which react with electron-deficient olefins, giving intermolecular addition products.

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页码：2017 / 2020

页数：4

相关论文

共 9 条

[1] PHENYL SELENOESTERS AS EFFECTIVE PRECURSORS OF ACYL RADICALS FOR USE IN INTERMOLECULAR ALKENE ADDITION-REACTIONS [J].

BOGER, DL ;

MATHVINK, RJ .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (08) :1777-1779

[2] HYDROXYCARBENE COMPLEXES FROM PARAMAGNETIC ACYLMETALS - ELECTROCHEMISTRY OF BENZOYLCHROMIUM(0) AND BENZOYLTUNGSTEN(0) CARBONYLS [J].

KLINGLER, RJ ;

HUFFMAN, JC ;

KOCHI, JK .

INORGANIC CHEMISTRY, 1981, 20 (01) :34-40

[3] GENERATION OF ALKYL RADICALS FROM 1-OXIDOALKYLIDENECHROMIUM(0) COMPLEXES BY OXIDATION WITH MANGANESE(III) 2-PYRIDINECARBOXYLATE AND THEIR REACTIONS WITH OLEFINS [J].

NARASAKA, K ;

SAKURAI, H .

CHEMISTRY LETTERS, 1993, (07) :1269-1272

[4]

PUNNIYAMURTHY T, 1994, J ORG CHEM, V459, P580

[5] FREE-RADICAL CARBONYLATION BY TTMSS MEDIATED PROCESS [J].

RYU, I ;

HASEGAWA, M ;

KURIHARA, A ;

OGAWA, A ;

TSUNOI, S ;

SONODA, N .

SYNLETT, 1993, (02) :143-145

[6] A CONVERGENT ENONE SYNTHESIS - 3-COMPONENT COUPLING OF ALKYL IODIDES, CARBON-MONOXIDE, AND ALLYLSTANNANES BY FREE-RADICAL CARBONYLATION [J].

RYU, I ;

YAMAZAKI, H ;

KUSANO, K ;

OGAWA, A ;

SONODA, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (22) :8558-8560

[7] DOUBLE ALKYLATION OF CARBON-MONOXIDE VIA FREE-RADICALS - SYNTHESIS OF UNSYMMETRICAL KETONES [J].

RYU, IH ;

KUSANO, K ;

YAMAZAKI, H ;

SONODA, N .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (17) :5003-5005

[8] CARBON-CARBON BOND FORMATION BY LIGHT-ASSISTED B-12 CATALYSIS - NUCLEOPHILIC ACYLATION OF MICHAEL OLEFINS [J].

SCHEFFOLD, R ;

ORLINSKI, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (24) :7200-7202

[9] OXIDATIVE CLEAVAGE OF TETRAMETHYLAMMONIUM PENTACARBONYL(1-OXYALKYLIDENE)CHROMATE(0) COMPLEXES - FORMATION OF CARBOXYLIC-ACID DERIVATIVES [J].

SODERBERG, BC ;

BOWDEN, BA .

ORGANOMETALLICS, 1992, 11 (06) :2220-2223