A DIMETHYLDIOXIRANE-MEDIATED ROUTE TO ENANTIOMERICALLY PURE TRICARBONYLCHROMIUM(0) COMPLEXES OF ORTHO-SUBSTITUTED STYRENES

被引：31

作者：

CHRISTIAN, PWN ^{[1
]}

GIL, R ^{[1
]}

MUNIZFERNANDEZ, K ^{[1
]}

THOMAS, SE ^{[1
]}

WIERZCHLEYSKI, AT ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 13期

关键词：

D O I：

10.1039/c39940001569

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dimethyldioxirane oxidation of tricarbonylchromium(0) complexes of a range of ortho-substituted (S)-alpha-methylbenzyldimethylamines 3a-f proceeds smoothly to give enantiomerically pure tricarbonylchromium(0) complexes of ortho-substituted styrenes 4a-f via chemoselective oxidation of the tertiary amines to their N-oxides and subsequent Cope reactions.

引用

页码：1569 / 1570

页数：2

共 15 条

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