COLLOIDAL SEMICONDUCTORS AS PHOTOCATALYSTS FOR SOLAR-ENERGY CONVERSION

被引：134

作者：

KAMAT, PV

DIMITRIJEVIC, NM

机构：

[1] Notre Dame Radiation Laboratory, Notre Dame

来源：

SOLAR ENERGY | 1990年 / 44卷 / 02期

关键词：

D O I：

10.1016/0038-092X(90)90070-S

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Considerable attention has been drawn in recent years to develop ultrafine semiconductor particles which exhibit excellent photocatalytic properties. Size quantization effects, nonlinear optical properties and enhanced photoredox properties make quantized colloidal semiconductors potentially useful in the design of photoelectrochemical systems. Photochemical and photophysical processes that directly influence the photocatalytic properties of the semiconductor colloids and the factors that limit the charge transfer at the semiconductor/electrolyte interface are discussed here. Applications of semiconductor particulate systems in the conversion and storage of solar energy are also described. © 1990.

引用

收藏

页码：83 / 98

页数：16

相关论文

共 290 条

[31] VISIBLE-LIGHT INDUCED GENERATION OF HYDROGEN FROM H2S IN CDS-DISPERSIONS, HOLE TRANSFER CATALYSIS BY RUO2 [J].

BORGARELLO, E ;

KALYANASUNDARAM, K ;

GRATZEL, M ;

PELIZZETTI, E .

HELVETICA CHIMICA ACTA, 1982, 65 (01) :243-248

[32] PHOTODECOMPOSITION OF H2S IN AQUEOUS ALKALINE MEDIA CATALYZED BY RUO2-LOADED ALUMINA IN THE PRESENCE OF CADMIUM-SULFIDE - APPLICATION OF THE INTER-PARTICLE ELECTRON-TRANSFER MECHANISM [J].

BORGARELLO, E ;

SERPONE, N ;

GRATZEL, M ;

PELIZZETTI, E .

INORGANICA CHIMICA ACTA, 1986, 112 (02) :197-201

[33] SUSTAINED WATER CLEAVAGE BY VISIBLE-LIGHT [J].

BORGARELLO, E ;

KIWI, J ;

PELIZZETTI, E ;

VISCA, M ;

GRATZEL, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (21) :6324-6329

[34] INTERFACIAL ELECTRON-TRANSFER IN TIO2 COLLOIDS [J].

BROWN, GT ;

DARWENT, JR ;

FLETCHER, PDI .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (23) :6446-6451

[35] PHOTOREDUCTION OF METHYL-ORANGE SENSITIZED BY COLLOIDAL TITANIUM-DIOXIDE [J].

BROWN, GT ;

DARWENT, JR .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1984, 80 :1631-1643

[36] METHYL-ORANGE AS A PROBE FOR PHOTOOXIDATION REACTIONS OF COLLOIDAL TIO2 [J].

BROWN, GT ;

DARWENT, JR .

JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (21) :4955-4959

[37]

BROWN GT, 1985, J CHEM SOC CHEM COMM, V98

[38] A SIMPLE-MODEL FOR THE IONIZATION-POTENTIAL, ELECTRON-AFFINITY, AND AQUEOUS REDOX POTENTIALS OF SMALL SEMICONDUCTOR CRYSTALLITES [J].

BRUS, LE .

JOURNAL OF CHEMICAL PHYSICS, 1983, 79 (11) :5566-5571

[39] ELECTRON ELECTRON AND ELECTRON-HOLE INTERACTIONS IN SMALL SEMICONDUCTOR CRYSTALLITES - THE SIZE DEPENDENCE OF THE LOWEST EXCITED ELECTRONIC STATE [J].

BRUS, LE .

JOURNAL OF CHEMICAL PHYSICS, 1984, 80 (09) :4403-4409

[40]

BUHLER N, 1984, J PHYS CHEM-US, V88, P3261, DOI 10.1021/j150659a025

← 1 2 3 4 5 6 7 8 9 10 →