CROWN-ETHER DERIVATIVES OF ANTHRAQUINONE AS IONOPHORES IN ION-SELECTIVE ELECTRODES

被引：11

作者：

ALLEN, JR

CYNKOWSKI, T

DESAI, J

BACHAS, LG

机构：

[1] UNIV KENTUCKY,DEPT CHEM,LEXINGTON,KY 40506

[2] UNIV KENTUCKY,CTR MEMBRANE SCI,LEXINGTON,KY 40506

[3] AGR UNIV WARSAW,INST GEN CHEM,PL-02528 WARSAW,POLAND

来源：

ELECTROANALYSIS | 1992年 / 4卷 / 05期

关键词：

IONOPHORE; ION SELECTIVE ELECTRODE; ANTHRAQUINONE; POTASSIUM;

D O I：

10.1002/elan.1140040504

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

1,8-anthraquinono-18-crown-6 and 10-[(2,4-dinitrophenyl)azo]-9-hydroxy-1,8-anthraceno-18-crown-6 were prepared from 1, 8-dichloroanthraquinone and used in the development of ion-selective electrodes. The electrodes based on 10-[(2,4-dinitrophenyl)azo]-9-hydroxy-1,8-anthraceno-18-crown-6 displayed better selectivity for potassium over sodium and had fewer interferences. The differences and similarities between the ionophores, as well as the optimum conditions for the preparation of the electrodes are discussed.

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页码：533 / 537

页数：5

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