A SIMPLE SYNTHESIS OF PRIMARY E-ALLYLIC AMINES FROM 1-TRIBUTYLSTANNYL-3-BIS(TRIMETHYLSILYL)AMINO PROP-1-ENE

被引：23

作者：

CORRIU, RJP

BOLIN, G

MOREAU, JJE

机构：

[1] Laboratoire Hétérochimie et Aminoacides, Associé au CNRS - Université de Montpellier II, Sciences et Techniques du Languedoc -, F 34095 Montpellier Cedex 05, Place E. Bataillon

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 33期

关键词：

D O I：

10.1016/S0040-4039(00)79880-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A facile and selective preparation of primary E-allylic amines is described from the readily available gamma-amino vinylic tin reagent 2, either by using the direct palladium catalysed coupling of the vinyl tin moitie or via conversion to a gamma-amino vinyl lithium reagent.

引用

页码：4121 / 4124

页数：4

共 35 条

[11] USES OF SI-N BONDS IN ORGANIC-SYNTHESIS - A DIRECT SYNTHESIS OF FUNCTIONAL PROTECTED PROPARGYLIC PRIMARY AMINES
CORRIU, RJP
HUYNH, V
MOREAU, JJE
[J]. TETRAHEDRON LETTERS, 1984, 25 (18) : 1887 - 1890
[12] SILYLAMINES IN ORGANIC-SYNTHESIS - A NEW ACCESS TO FUNCTIONAL PYRROLES VIA ORGANOCUPRATES ADDITION ON METHYL-BIS(TRIMETHYLSILYL)AMINOMETHYLPROPIOLATE
CORRIU, RJP
MOREAU, JJE
VERNHET, C
[J]. TETRAHEDRON LETTERS, 1987, 28 (26) : 2963 - 2966
[13] A FACILE SYNTHESIS OF NEW TETRAPYRROLE MACROCYCLIC DERIVATIVES - FORMATION OF BIMETALLIC TRANSITION-METAL COMPLEXES
CORRIU, RJP
BOLIN, G
MOREAU, JJE
VERNHET, C
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (04) : 211 - 213
[14] NEW PREPARATION OF N,N-BIS(TRIMETHYLSILYL)ENAMINES VIA IRON CARBONYL PHOTOCATALYZED ISOMERIZATION OF UNSATURATED AMINES
CORRIU, RJP
HUYNH, V
MOREAU, JJE
PATAUDSAT, M
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 255 (03) : 359 - 364
[15] PALLADIUM(0) CATALYZED COUPLING OF TRANS-1,2-BIS(TRI-N-BUTYLSTANNYL)ETHYLENE WITH AROMATIC HALIDES - A CONVENIENT SYNTHESIS OF SUBSTITUTED TRANS-BETA-BROMOSTYRENES
HAACK, RA
PENNING, TD
DJURIC, SW
DZIUBA, JA
[J]. TETRAHEDRON LETTERS, 1988, 29 (23) : 2783 - 2786
[16] METALATED NITROGEN DERIVATIVES OF CARBONIC-ACID IN ORGANIC-SYNTHESIS .28. THE HOMOALDOL REACTION, OR HOW TO OVERCOME PROBLEMS OF REGIO-SELECTIVITY AND STEREO-SELECTIVITY
HOPPE, D
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (12): : 932 - 948
[17] BIS(METHOXYCARBONYL)SULFUR DIIMIDE, A CONVENIENT REAGENT FOR THE ALLYLIC AMINATION OF ALKENES
KRESZE, G
MUNSTERER, H
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (20) : 3561 - 3564
[18] PALLADIUM-CATALYZED COUPLING OF 2-BROMOANILINES WITH VINYLSTANNANES - A REGIOCONTROLLED SYNTHESIS OF SUBSTITUTED INDOLES
KROLSKI, ME
RENALDO, AF
RUDISILL, DE
STILLE, JK
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (06) : 1170 - 1176
[19] LAURENT A, 1984, J CHEM RES-S, P354
[20] PALLADIUM-CATALYZED SYNTHESIS OF CINNAMYLAMINES
MALEK, NJ
MOORMANN, AE
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (27) : 5395 - 5397

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