ENANTIOSELECTIVITY FOR HYDROPHOSPHONYLATION OF AROMATIC-ALDEHYDES CATALYZED BY LANTHANUM BINAPHTHOL COMPLEX - REMARKABLE ELECTRONIC EFFECT OF AROMATIC SUBSTITUENTS

被引：123

作者：

YOKOMATSU, T ^{[1
]}

YAMAGISHI, T ^{[1
]}

SHIBUYA, S ^{[1
]}

机构：

[1] TOKYO COLL PHARM,1432-1 HORINOUCHI,HACHIOJI,TOKYO 19203,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 08期

关键词：

D O I：

10.1016/S0957-4166(00)80416-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrophosphonylation of aromatic aldehydes with diethyl phosphite in the presence of catalytic amount of La-BINOL complex (2) proceeded enantioselectively to give the corresponding alpha-hydroxyphosphonates in good yield. Enantioselectivity was found to depend on the electronic nature of para-substituents.

引用

页码：1783 / 1784

页数：2

共 6 条

[1] A NEW PREPARATION OF LANTHANIDE ALKOXIDES, AND SOME APPLICATIONS IN CATALYSIS
LEBRUN, A
NAMY, JL
KAGAN, HB
[J]. TETRAHEDRON LETTERS, 1991, 32 (21) : 2355 - 2358
[2] LANTHANOID(III) ALKOXIDES AS NOVEL CATALYSTS FOR A RAPID TRANSHYDROCYANATION FROM ACETONE CYANOHYDRIN TO ALDEHYDES AND KETONES
OHNO, H
MORI, A
INOUE, S
[J]. CHEMISTRY LETTERS, 1993, (02) : 375 - 378
[3] CATALYTIC ASYMMETRIC NITROALDOL REACTIONS - A NEW PRACTICAL METHOD FOR THE PREPARATION OF THE OPTICALLY-ACTIVE LANTHANUM COMPLEX
SASAI, H
SUZUKI, T
ITOH, N
SHIBASAKI, M
[J]. TETRAHEDRON LETTERS, 1993, 34 (05) : 851 - 854
[4] CATALYTIC ASYMMETRIC NITROALDOL REACTION - AN EFFICIENT SYNTHESIS OF (S) PROPRANOLOL USING THE LANTHANUM BINAPHTHOL COMPLEX
SASAI, H
ITOH, N
SUZUKI, T
SHIBASAKI, M
[J]. TETRAHEDRON LETTERS, 1993, 34 (05) : 855 - 858
[5] BASIC CHARACTER OF RARE-EARTH-METAL ALKOXIDES - UTILIZATION IN CATALYTIC C-C BOND-FORMING REACTIONS AND CATALYTIC ASYMMETRIC NITROALDOL REACTIONS
SASAI, H
SUZUKI, T
ARAI, S
ARAI, T
SHIBASAKI, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (11) : 4418 - 4420
[6] ENANTIOSELECTIVITY FOR HYDROPHOSPHONYLATION OF AROMATIC-ALDEHYDES CATALYZED BY LANTHANUM BINAPHTHOL COMPLEX - REMARKABLE ELECTRONIC EFFECT OF AROMATIC SUBSTITUENTS
YOKOMATSU, T
YAMAGISHI, T
SHIBUYA, S
[J]. TETRAHEDRON-ASYMMETRY, 1993, 4 (08) : 1783 - 1784

← 1 →