OXYFUNCTIONALIZATION REACTIONS BY PERFLUORO CIS-2,3-DIALKYTOXAZIRIDINES - ENANTIOSELECTIVE CONVERSION OF SILANES INTO SILANOLS

被引：42

作者：

CAVICCHIOLI, M ^{[1
]}

MONTANARI, V ^{[1
]}

RESNATI, G ^{[1
]}

机构：

[1] POLITECN MILAN,DIPARTIMENTO CHIM,CTR STUDIO SOSTANZE ORGAN NAT,CNR,I-20131 MILAN,ITALY

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 34期

关键词：

D O I：

10.1016/S0040-4039(00)73424-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Perfluoro cis-2,3-dialkyloxaziridine 2 is shown to perform the oxyfunctionalization of silanes 1 under very mild conditions to give silanols and silanediols 3 in high chemical yields and complete enantioselectivity.

引用

页码：6329 / 6330

页数：2

共 10 条

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