A PSEUDO-JAHN-TELLER TREATMENT OF THE PSEUDOROTATIONAL SPECTRUM OF NA3

被引：75

作者：

MEISWINKEL, R

KOPPEL, H

机构：

[1] Theoretical Chemistry, Institute of Physical Chemistry, INF 253, University of Heidelberg

来源：

CHEMICAL PHYSICS | 1990年 / 144卷 / 01期

关键词：

D O I：

10.1016/0301-0104(90)80077-B

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The B system of the two-photon ionization spectrum of Na3 is re-investigated theoretically, paying special attention to the influence of a nearby electronic state on the pseudorotational motion. It is found that the pseudo-Jahn-Teller coupling to this state can well account for the energy level structure and intensity distribution of the B system. The Jahn-Teller effect invoked previously in this context is possibly only of minor importance. The implications of these findings for the topological phase are discussed. © 1990.

引用

页码：117 / 128

页数：12

共 47 条

[41] STATIC ELECTRIC-DIPOLE POLARIZABILITY OF SMALL SODIUM AGGREGATES
MOULLET, I
MARTINS, JL
REUSE, F
BUTTET, J
[J]. ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS, 1989, 12 (1-4): : 353 - 356
[42] STURGE MD, 1967, SOLID STATE PHYSICS, V20
[43] CONSISTENT ANALYTIC REPRESENTATION OF THE 2 LOWEST POTENTIAL-ENERGY SURFACES FOR LI-3, NA-3, AND K-3
THOMPSON, TC
IZMIRLIAN, G
LEMON, SJ
TRUHLAR, DG
MEAD, CA
[J]. JOURNAL OF CHEMICAL PHYSICS, 1985, 82 (12) : 5597 - 5603
[44] ON THE FORM OF THE ADIABATIC AND DIABATIC REPRESENTATION AND THE VALIDITY OF THE ADIABATIC APPROXIMATION FOR X3 JAHN-TELLER SYSTEMS
THOMPSON, TC
TRUHLAR, DG
MEAD, CA
[J]. JOURNAL OF CHEMICAL PHYSICS, 1985, 82 (05) : 2392 - 2407
[45] VIBRONIC INTERACTION IN LOWER ELECTRONIC STATES OF BENZENE .I. REVIEW OF STATIC PROBLEM AND SOLUTION OF PSEUDO-CYLINDRICAL VIBRONIC EQUATIONS
VANDERWA.JH
BERGHUIS, AM
DEGROOT, MS
[J]. MOLECULAR PHYSICS, 1967, 13 (04) : 301 - &
[46] JAHN-TELLER, PSEUDO JAHN-TELLER COUPLING, AND CIRCULAR-DICHROISM SPECTRA OF (E+A) STAR-E SYSTEMS
ZGIERSKI, MZ
PAWLIKOWSKI, M
[J]. JOURNAL OF CHEMICAL PHYSICS, 1979, 70 (07) : 3444 - 3452
[47] TOPOLOGICAL PHASE IN MOLECULAR BOUND-STATES - APPLICATION TO THE E X E SYSTEM
ZWANZIGER, JW
GRANT, ER
[J]. JOURNAL OF CHEMICAL PHYSICS, 1987, 87 (05) : 2954 - 2964

← 1 2 3 4 5 →