PHENOLIC OXIDATIONS WITH PHENYLIODONIUM DIACETATE

被引：140

作者：

PELTER, A

ELGENDY, SMA

机构：

[1] Department of Chemistry, University of Swansea, Swansea, SA2 8PP, Singleton Park

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 16期

关键词：

D O I：

10.1039/p19930001891

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Phenyliodonium diacetate (PIDA) in methanol interacts smoothly with phenols to yield p-quinones, o-quinones, 4,4-dialkoxycyclohexa-2,5-dienones or 4-alkyl-4-alkoxycyclohexa-2,5-dienones, dependant on the constitution of the phenolic substrate. The reactions proceed in mild conditions and good yields and are synthetically useful.

引用

页码：1891 / 1896

页数：6

共 75 条

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