LIQUID-PHASE FLUORINATION AND DEHYDROCHLORINATION OF 1,1,1-TRICHLOROETHANE

被引：4

作者：

BRUNET, S ^{[1
]}

BATIOT, C ^{[1
]}

BARRAULT, J ^{[1
]}

BLANCHARD, M ^{[1
]}

COUSTARD, JM ^{[1
]}

机构：

[1] ESIP,CATALYSE LAB,CNRS,URA 350,40 AVE RECTEUR PINEAU,F-86022 POITIERS,FRANCE

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 63卷 / 03期

关键词：

D O I：

10.1016/S0022-1139(00)80566-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

During the liquid-phase fluorination of 1,1,1-trichloroethane with SbCl5.HF, 1,1-dichloroethene is formed. This reacts to give linear and branched oligomers. The hydrolysis of these by-products affords 3,4-dichlorophenol, 6-methyl-4-chloro-2-pyran-2-one and 2-methyl-5,7-dichlorochromone whose source is the acid-catalyzed reaction of water with the trimer and pentamer of 1,1-dichloroethene.

引用

页码：227 / 232

页数：6

共 11 条

[1]

Breitmaier E., 1987, CARBON 13 NMR SPECTR, P279

[2] LIQUID-PHASE FLUORINATION OF 1,1,1-TRICHLOROETHANE [J].

BRUNET, S ;

BATIOT, C ;

BARRAULT, J ;

BLANCHARD, M .

JOURNAL OF FLUORINE CHEMISTRY, 1992, 59 (01) :33-39

[3]

CHEMINAL B, 1991, Patent No. 5055624

[4]

FEINSCHILD G, 1991, Patent No. 40059456

[5]

FEINSCHILD G, 1991, Patent No. 40059448

[6]

KULIKOVA AE, 1971, RUSS CHEM REV, V40, P256, DOI DOI 10.1070/RC1971V040N03ABEH001917

[7]

LANTZ A, 1991, Patent No. 415814

[8] ALUMINUM(III) CHLORIDE CHLOROHYDROCARBON CHEMISTRY - FOURIER-TRANSFORM INFRARED SPECTROSCOPIC STUDIES OF THE REACTIONS BETWEEN SOLID ALUMINUM(III) CHLORIDE AND 1,1,1-TRICHLOROETHANE OR 1,1-DICHLOROETHENE VAPORS [J].

MCBETH, DG ;

WINFIELD, JM ;

COOK, BW ;

WINTERTON, N .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (02) :671-676

[9] FLUORINATED GAMMA-ALUMINA - CATALYTIC FLUORINATION OF 1,1,1-TRICHLOROETHANE AT AMBIENT-TEMPERATURE [J].

THOMSON, J ;

WEBB, G ;

WINFIELD, JM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (05) :323-324

[10]

1991, Patent No. 407689

← 1 2 →