CHARACTERIZATION OF DIAMOND-LIKE CARBON BY INFRARED-SPECTROSCOPY

被引:147
作者
GRILL, A
PATEL, V
机构
[1] IBM Research Division, T. J. Watson Research Center, Yorktown Heights
关键词
D O I
10.1063/1.107098
中图分类号
O59 [应用物理学];
学科分类号
摘要
Comparison of Fourier transform infrared (FTIR) absorption spectroscopy, high resolution C-13 nuclear magnetic resonance spectroscopy, and hydrogen evaluation by forward recoil elastic scattering (FRES) measurements shows that FTIR cannot be used to determine the carbon hybridization or total hydrogen content of diamondlike carbon films (DLC). FTIR absorption reflects only the optically active hydrogen in the DLC and, using it together with FRES, it can provide an estimate of the unbound hydrogen contained in the films. The fraction of unbound hydrogen can reach values of up to approximately 50%.
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页码:2089 / 2091
页数:3
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