SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF TRANS-BIS(2,6-DIISOPROPYLPHENYLIMIDO)BIS-(TRIMETHYLPHOSPHINO)RUTHENIUM(IV) - THE 1ST STRUCTURAL DETERMINATION OF A TERMINAL IMIDO RUTHENIUM COMPOUND

被引:42
作者
DANOPOULOS, AA
WILKINSON, G
HUSSAINBATES, B
HURSTHOUSE, MB
机构
[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,JOHNSON MATTHEY LAB,LONDON SW7 2AY,ENGLAND
[2] UNIV WALES CARDIFF,SCH CHEM & APPL CHEM,CARDIFF CF1 3TB,WALES
关键词
D O I
10.1016/S0277-5387(00)83602-5
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Interaction of trans-RuCl2(PMe3)4 and Li(2,6-Pri2C6H3NH) in THF gives an orange solution which, on oxidation by O2, gives blue trans-(2,6-Pri2C6H3N)2Ru(PMe3)2 which has been shown to have a planar structure by X-ray diffraction study.
引用
收藏
页码:2961 / 2964
页数:4
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