A MODEL FOR ALPHA-KETO ACID-DEPENDENT NONHEME IRON ENZYMES - STRUCTURE AND REACTIVITY OF [FE-2(II)(ME(2)HDP)(2)(BF)](CLO4)

被引：13

作者：

CHIOU, YM ^{[1
]}

QUE, L ^{[1
]}

机构：

[1] UNIV MINNESOTA,DEPT CHEM,MINNEAPOLIS,MN 55455

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 18期

关键词：

D O I：

10.1002/anie.199418861

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The bis(μ‐phenolato)diiron(II) complex 1 is a model compound for nonheme iron enzymes that use α‐keto acids as cofactors. Complex 1 undergoes immediate oxidative decarboxylation upon exposure to dioxygen at a rate which is three to four orders of magnitude faster than those observed for other compounds of this type. The formula of the ligand is given under that of 1. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1886 / 1888

页数：3

共 32 条

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