ON THE MECHANISM OF ASYMMETRIC DIHYDROXYLATION (AD) OF ALKENES

被引：8

作者：

LOHRAY, BB

BHUSHAN, V

NANDANAN, E

机构：

[1] Division of Organic Chemistry-Synthesis, National Chemical Laboratory, Pune

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 24期

关键词：

D O I：

10.1016/S0040-4039(00)73153-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

H-1 NMR studies on bis(9-O-dihydroquinidinyl)terephthalate (DHQD(2)-TP) with various concentrations of osmium tetroxide and trans-2-hexene reveal that OsO4 is bound to both the quinuclidine moieties of DHQD(2)-TP but only one or the bound OsO4 reacts with alkenes in the AD process.

引用

页码：4209 / 4210

页数：2

共 4 条

[1] TEMPERATURE EFFECTS IN ASYMMETRIC DIHYDROXYLATION - EVIDENCE FOR A STEPWISE MECHANISM
GOBEL, T
SHARPLESS, KB
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (09): : 1329 - 1331
[2] ON THE MECHANISM OF OSMIUM CATALYZED ASYMMETRIC DIHYDROXYLATION (ADH) OF ALKENES
LOHRAY, BB
BHUSHAN, V
[J]. TETRAHEDRON LETTERS, 1992, 33 (35) : 5113 - 5116
[3] RECENT ADVANCES IN THE ASYMMETRIC DIHYDROXYLATION OF ALKENES
LOHRAY, BB
[J]. TETRAHEDRON-ASYMMETRY, 1992, 3 (11) : 1317 - 1349
[4] SHARPLESS, 1993, J AM CHEM SOC, V115, P12226

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