STEREOCONTROLLED REDUCTION OF BETA-KETOESTERS BY GEOTRICHUM-CANDIDUM - PREPARATION OF D-3-HYDROXYALKANOATES

被引：19

作者：

BUISSON, D ^{[1
]}

AZERAD, R ^{[1
]}

SANNER, C ^{[1
]}

LARCHEVEQUE, M ^{[1
]}

机构：

[1] ECOLE NORM SUPER,CNRS,UPR 402,CHIM LAB,F-75231 PARIS 05,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 10期

关键词：

MICROBIAL REDUCTION; GEOTRICHUM-CANDIDUM; BETA-KETOESTERS; D-3-HYDROXYALKANOATES;

D O I：

10.1016/S0957-4166(00)86143-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Geotrichum candidum has been used for the preparative reduction of beta-oxoalkanoic esters to the corresponding D-beta-hydroxyesters. The stereospecificity for ethyl 3-oxobutanoate or 3-oxopentanoate is markedly increased by preincubation of the mycelium before addition of the substrate.

引用

页码：987 / 988

页数：2

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