SOLID-STATE REACTIONS OF IRIDIUM(I)-1,5-CYCLOOCTADIENE COMPOUNDS WITH CO - SYNTHESIS OF CATIONIC (1,5-CYCLOOCTADIENE)CARBONYLIRIDIUM(I) COMPLEXES

被引：15

作者：

CHIN, CS ^{[1
]}

LEE, B ^{[1
]}

KIM, S ^{[1
]}

机构：

[1] LUCKY LTD,BIOTECHNOL,CTR R & D,TAEJON 305343,SOUTH KOREA

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 04期

关键词：

D O I：

10.1021/om00028a077

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Ir(COD)(CO)2(L)]ClO4 (1) and [Ir(COD)(CO)(L)2] ClO4 (2) (COD = 1,5-cyclooctadiene; L = PPh3 (a), AsPh3 (b)) have been prepared from the solid-state reactions of [Ir(COD)(L)(PhCN)]ClO4 (3) and [Ir(COD)(L)2]ClO4 (4), respectively, with CO (1 atm) at 25-degrees-C. The products 1 and 2 have been characterized by conventional analytical and spectroscopic methods as well as single-crystal X-ray crystallographic analysis for [Ir(COD)(CO)2(PPh3)]ClO4 (1a) and [Ir(COD) (CO)2(ASPh3)] ClO4 (1b).

引用

页码：1462 / 1466

页数：5

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