ASYMMETRIC-SYNTHESIS OF BIARYLS BY INTRAMOLECULAR OXIDATIVE COUPLINGS OF CYANOCUPRATE INTERMEDIATES

被引:134
作者
LIPSHUTZ, BH
KAYSER, F
LIU, ZP
机构
[1] Department of Chemistry, University of California, Santa Barbara, California
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 18期
关键词
D O I
10.1002/anie.199418421
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
With a judicious choice of tether from the “chiral pool”, coupling of the two aryl rings in nonracemic 1 yields only one of the two possible diastereomers of biaryl 2. G  C or O substituent; R, R′  H, 3OMe. This method is expected to be widely applicable. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany
引用
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页码:1842 / 1844
页数:3
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