ENANTIOSELECTIVE SYNTHESIS OF EPOXIDES VIA SHARPLESS EPOXIDATION OF ALKENYLSILANOLS

被引:34
作者
CHAN, TH [1 ]
CHEN, LM [1 ]
WANG, D [1 ]
LI, LH [1 ]
机构
[1] CHINESE ACAD SCI,INST CHEM,BEIJING,PEOPLES R CHINA
来源
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1993年 / 71卷 / 01期
关键词
D O I
10.1139/v93-009
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Enantioselective synthesis of simple epoxides can be achieved by Sharpless epoxidation of alkenylsilanols followed by protodesilylation of the chiral epoxysilanols. The approach has been applied to the synthesis of frontalin.
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页码:60 / 67
页数:8
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