PHASE-TRANSITIONS IN SELF-ASSEMBLED MONOLAYERS DETECTED BY ELECTROCHEMISTRY

被引：56

作者：

BADIA, A

BACK, R

LENNOX, RB

机构：

[1] MCGILL UNIV,DEPT CHEM,MONTREAL H3A 2K6,PQ,CANADA

[2] MAX PLANCK INST POLYMER RES,MAINZ,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 22期

关键词：

D O I：

10.1002/anie.199423321

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Order–disorder transitions in alkanethiol monolayers (schematic representation below) have been detected by temperature‐dependent electrochemistry of a redox pair at a gold electrode with alkanethiols. The electron transfer is clearly not a result of electron tunneling, but instead involves a permeability of the monolayer to the redox species. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

收藏

页码：2332 / 2335

页数：4

相关论文

共 61 条

[1]

BADIA A, UNPUB

[2] MODELING ORGANIC-SURFACES WITH SELF-ASSEMBLED MONOLAYERS [J].

BAIN, CD ;

WHITESIDES, GM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (04) :506-512

[3] FORMATION OF MONOLAYER FILMS BY THE SPONTANEOUS ASSEMBLY OF ORGANIC THIOLS FROM SOLUTION ONTO GOLD [J].

BAIN, CD ;

TROUGHTON, EB ;

TAO, YT ;

EVALL, J ;

WHITESIDES, GM ;

NUZZO, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (01) :321-335

[4]

BAIN CD, 1989, ANGEW CHEM, V101, P522

[5] X-RAY-DIFFRACTION STUDY OF A LANGMUIR MONOLAYER OF C21H43OH [J].

BARTON, SW ;

THOMAS, BN ;

FLOM, EB ;

RICE, SA ;

LIN, B ;

PENG, JB ;

KETTERSON, JB ;

DUTTA, P .

JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (04) :2257-2270

[6] ELECTROCHEMISTRY AT OMEGA-HYDROXY THIOL COATED ELECTRODES .4. COMPARISON OF THE DOUBLE-LAYER AT OMEGA-HYDROXY THIOL AND ALKANETHIOL MONOLAYER COATED AU ELECTRODES [J].

BECKA, AM ;

MILLER, CJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (23) :6233-6239

[7] ELECTROCHEMISTRY AT OMEGA-HYDROXY THIOL COATED ELECTRODES .3. VOLTAGE INDEPENDENCE OF THE ELECTRON-TUNNELING BARRIER AND MEASUREMENTS OF REDOX KINETICS AT LARGE OVERPOTENTIALS [J].

BECKA, AM ;

MILLER, CJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (06) :2657-2668

[8] SYNTHESIS OF A RIGID DIMETHOXYNAPHTHALENE SPACER DITHIOL WHICH SPONTANEOUSLY ATTACHES TO AU AND PT ELECTRODES - PROPERTIES OF MONOLAYER FILMS IN NONAQUEOUS SOLVENTS [J].

BLACK, AJ ;

WOOSTER, TT ;

GEIGER, WE ;

PADDONROW, MN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (17) :7924-7925

[9] SUBSTRATE DEPENDENCE OF THE SURFACE-STRUCTURE AND CHAIN PACKING OF DOCOSYL MERCAPTAN SELF-ASSEMBLED ON THE (111), (110), AND (100) FACES OF SINGLE-CRYSTAL GOLD [J].

CAMILLONE, N ;

CHIDSEY, CED ;

LIU, G ;

SCOLES, G .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (05) :4234-4245

[10] SUPERLATTICE STRUCTURE AT THE SURFACE OF A MONOLAYER OF OCTADECANETHIOL SELF-ASSEMBLED ON AU(111) [J].

CAMILLONE, N ;

CHIDSEY, CED ;

LIU, GY ;

SCOLES, G .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (04) :3503-3511

← 1 2 3 4 5 6 7 →