PHASE-TRANSITIONS IN SELF-ASSEMBLED MONOLAYERS DETECTED BY ELECTROCHEMISTRY

被引：56

作者：

BADIA, A

BACK, R

LENNOX, RB

机构：

[1] MCGILL UNIV,DEPT CHEM,MONTREAL H3A 2K6,PQ,CANADA

[2] MAX PLANCK INST POLYMER RES,MAINZ,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 22期

关键词：

D O I：

10.1002/anie.199423321

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Order–disorder transitions in alkanethiol monolayers (schematic representation below) have been detected by temperature‐dependent electrochemistry of a redox pair at a gold electrode with alkanethiols. The electron transfer is clearly not a result of electron tunneling, but instead involves a permeability of the monolayer to the redox species. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

收藏

页码：2332 / 2335

页数：4

相关论文

共 61 条

[31]

FOX MA, 1990, LANGMUIR, V6, P1617

[32]

HAHNER G, 1993, LANGMUIR, V9, P1955

[33] TRANSMEMBRANE ELECTRON-TRANSFER MEDIATED BY DIHEPTYLVIOLOGEN - DISPROPORTIONATION OF VIOLOGEN RADICAL AND VIOLOGEN-INDUCED LEAKAGE OF EXTERNAL REDUCTANT [J].

HAMMARSTROM, L ;

BERGLUND, H ;

ALMGREN, M .

JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (38) :9588-9593

[34] MOLECULAR-DYNAMICS SIMULATION OF THE EFFECTS OF TEMPERATURE ON A DENSE MONOLAYER OF LONG-CHAIN MOLECULES [J].

HAUTMAN, J ;

KLEIN, ML .

JOURNAL OF CHEMICAL PHYSICS, 1990, 93 (10) :7483-7492

[35] SELECTIVE FUNCTIONALIZATION OF GOLD MICROSTRUCTURES WITH FERROCENYL DERIVATIVES VIA REACTION WITH THIOLS OR DISULFIDES - CHARACTERIZATION BY ELECTROCHEMISTRY AND AUGER-ELECTRON SPECTROSCOPY [J].

HICKMAN, JJ ;

OFER, D ;

ZOU, CF ;

WRIGHTON, MS ;

LAIBINIS, PE ;

WHITESIDES, GM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (04) :1128-1132

[36] ELECTRON-TRANSFER IN SELF-ASSEMBLED MONOLAYERS OF N-METHYL-N'-CARBOXYALKYL-4,4'-BIPYRIDINIUM LINKED TO GOLD ELECTRODES [J].

KATZ, E ;

ITZHAK, N ;

WILLNER, I .

LANGMUIR, 1993, 9 (05) :1392-1396

[37] OBSERVATION OF N-OCTADECANETHIOL MULTILAYER FORMATION FROM SOLUTION ONTO GOLD [J].

KIM, YT ;

MCCARLEY, RL ;

BARD, AJ .

LANGMUIR, 1993, 9 (08) :1941-1944

[38] AN X-RAY-SCATTERING STUDY OF LIPID MONOLAYERS AT THE AIR WATER INTERFACE AND ON SOLID SUPPORTS [J].

KJAER, K ;

ALSNIELSEN, J ;

HELM, CA ;

TIPPMANNKRAYER, P ;

MOHWALD, H .

THIN SOLID FILMS, 1988, 159 :17-28

[39]

LAIBINIS PE, 1991, J AM CHEM SOC, V113, P7167

[40] ELECTROGENIC AND ELECTRONEUTRAL PATHWAYS FOR METHYL VIOLOGEN-MEDIATED TRANSMEMBRANE OXIDATION-REDUCTION ACROSS DIHEXADECYLPHOSPHATE VESICULAR MEMBRANES [J].

LYMAR, SV ;

HURST, JK .

JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (03) :989-996

← 1 2 3 4 5 6 7 →