PHASE-TRANSITIONS IN SELF-ASSEMBLED MONOLAYERS DETECTED BY ELECTROCHEMISTRY

被引：56

作者：

BADIA, A

BACK, R

LENNOX, RB

机构：

[1] MCGILL UNIV,DEPT CHEM,MONTREAL H3A 2K6,PQ,CANADA

[2] MAX PLANCK INST POLYMER RES,MAINZ,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 22期

关键词：

D O I：

10.1002/anie.199423321

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Order–disorder transitions in alkanethiol monolayers (schematic representation below) have been detected by temperature‐dependent electrochemistry of a redox pair at a gold electrode with alkanethiols. The electron transfer is clearly not a result of electron tunneling, but instead involves a permeability of the monolayer to the redox species. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：2332 / 2335

页数：4

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