1ST ISOLABLE TERT-ALKYL PHENYL SELONES

被引：15

作者：

ISHII, A ^{[1
]}

DING, MX ^{[1
]}

NAKAYAMA, J ^{[1
]}

HOSHINO, M ^{[1
]}

机构：

[1] SAITAMA UNIV, FAC SCI, DEPT CHEM, URAWA, SAITAMA 338, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 12期

关键词：

D O I：

10.1246/cl.1992.2289

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of the dihydrazone of 2,2,6,6-tetramethyl-1,7-diphenyl-1,7-dione with Se2Cl2 in refluxing benzene in the presence of tributylamine gave the corresponding 1-oxo-7-selone and 1,7-diselone derivatives in 14 and 33% yields, respectively, while similar reaction of the dihydrazone of 2,2,5,5-tetramethyl-1,6-diphenyl-1,6-dione gave bicyclic 1,3-diselenetane (25%), 1,2,4-triselenolane (20%), and cyclohexene (12%) derivatives by intramolecular cyclizations.

引用

页码：2289 / 2292

页数：4

共 25 条

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