1,2-ASYMMETRIC INDUCTION IN RADICAL-MEDIATED ALLYLATION OF DIETHYL (2S,3S)-3-BROMO-2-OXYSUCCINATES - EFFICIENT STEREOSELECTIVITY ENHANCEMENT BY COMPLEXATION WITH EU(FOD)(3)

被引：30

作者：

NAGANO, H

KUNO, Y

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 08期

关键词：

D O I：

10.1039/c39940000987

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Allylation of diethyl (2S, 3S)-3-bromo-2-trimethylsilyoxysuccinate with allyltributyltin in the presence of Eu(fod)(3) was found to give diethyl (2R, 3R)-3-allyl-2-trimethylsilyloxysuccinate with high diastereoselectivity [(2R, 3R):(2R, 3S) = 8.6:1].

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页码：987 / 988

页数：2

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