A REGIOCHEMICAL CONTROL IN THE PI-ALLYLPALLADIUM SUBSTITUTION - PREPARATION OF OPTICALLY-ACTIVE GAMMA-SILYLALLYLAMINES

被引:32
作者
INAMI, H [1 ]
ITO, T [1 ]
URABE, H [1 ]
SATO, F [1 ]
机构
[1] TOKYO INST TECHNOL,DEPT BIOMOLEC ENGN,4259 NAGATSUTA CHO,MIDORI KU,YOKOHAMA,KANAGAWA 227,JAPAN
关键词
D O I
10.1016/S0040-4039(00)73814-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Optically active gamma-trimethysilylallylamine derivatives were prepared from gamma-trimethylsilylallyl alcohols via i. derivatization to carbonates and ii. palladium-catalyzed, regioselective allylic substitution by nitrogen nucleophiles without loss of the enantiomeric purities of the starting alcohols.
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页码:5919 / 5922
页数:4
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