A REGIOCHEMICAL CONTROL IN THE PI-ALLYLPALLADIUM SUBSTITUTION - PREPARATION OF OPTICALLY-ACTIVE GAMMA-SILYLALLYLAMINES

被引：32

作者：

INAMI, H ^{[1
]}

ITO, T ^{[1
]}

URABE, H ^{[1
]}

SATO, F ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT BIOMOLEC ENGN,4259 NAGATSUTA CHO,MIDORI KU,YOKOHAMA,KANAGAWA 227,JAPAN

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 37期

关键词：

D O I：

10.1016/S0040-4039(00)73814-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Optically active gamma-trimethysilylallylamine derivatives were prepared from gamma-trimethylsilylallyl alcohols via i. derivatization to carbonates and ii. palladium-catalyzed, regioselective allylic substitution by nitrogen nucleophiles without loss of the enantiomeric purities of the starting alcohols.

引用

页码：5919 / 5922

页数：4

共 35 条

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