STRUCTURAL EFFECTS ON THE ENANTIOSELECTIVE ACETYLATION OF 4-HYDROXYCHROMANS CATALYZED BY MICROBIAL LIPASES

被引：23

作者：

MAJERIC, M

GELOPUJIC, M

SUNJIC, V

LEVAI, A

SEBOK, P

TIMAR, T

机构：

[1] RUDJER BOSKOVIC INST,ZAGREB 41001,CROATIA

[2] LAJOS KOSSUTH UNIV,DEPT ORGAN CHEM,H-4010 DEBRECEN,HUNGARY

[3] ALKALOIDA CHEM CO LTD,H-4440 TISZAVASVARI,HUNGARY

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 04期

关键词：

D O I：

10.1016/0957-4166(95)00103-V

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Kinetic resolutions of a series of racemic 4-hydroxychromans by the Candida cylindracea lipase catalysed acetylation are described. Correlation between structure (conformation) and enantioselectivity is discussed.

引用

页码：937 / 944

页数：8

共 15 条

[1]

Ellis G.P., 1977, CHROMENES CHROMANONE

[2]

FABER K, 1992, BIOTRANSFORMATIONS O, P86

[3] ENZYMATIC KINETIC SEPARATION OF STEREOISOMERIC MACROCYCLIC LACTONE DERIVATIVES, 7-ALPHA,BETA-O-ACYL TRANS-ZEARALENOLS AND 7-ALPHA,BETA-O-ACYL ZEARANOLS [J].

GELO, M ;

SUNJIC, V .

TETRAHEDRON, 1992, 48 (31) :6511-6520

[4]

GELO M, 1994, IN PRESS TETRAHEDRON

[5] ENANTIOSELECTIVE HYDROLYSIS OF SOME 3-(2-NITROPHENOXY) BUTANOATES CATALYZED BY PSEUDOMONAS-FLUORESCENS AND PSEUDOMONAS-SP LIPASE [J].

KNEZOVIC, S ;

SUNJIC, V ;

LEVAI, A .

TETRAHEDRON-ASYMMETRY, 1993, 4 (03) :313-320

[6] LIPASE-CATALYZED ESTER FORMATION IN ORGANIC-SOLVENTS AN EASY PREPARATIVE RESOLUTION OF ALPHA-SUBSTITUTED CYCLOHEXANOLS [J].

LANGRAND, G ;

SECCHI, M ;

BUONO, G ;

BARATTI, J ;

TRIANTAPHYLIDES, C .

TETRAHEDRON LETTERS, 1985, 26 (15) :1857-1860

[7] ENZYMIC PREPARATION OF ENANTIOMERICALLY PURE CYCLOHEXANOLS - ESTER SYNTHESIS BY IRREVERSIBLE ACYL TRANSFER [J].

LAUMEN, K ;

SEEMAYER, R ;

SCHNEIDER, MP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (01) :49-51

[8] SYNTHESIS OF BENZOPYRAN DERIVATIVES .15. PREPARATION OF ARYLSULFONYLOXY-2,2-DIMETHYL-2H-CHROMENES [J].

LEVAI, A ;

TOTH, G ;

SZOLLOSY, A ;

TIMAR, T .

MONATSHEFTE FUR CHEMIE, 1990, 121 (05) :403-411

[9] LIPASE YS-CATALYZED ACYLATION OF ALCOHOLS - A PREDICTIVE ACTIVE-SITE MODEL FOR LIPASE YS TO IDENTIFY WHICH ENANTIOMER OF A PRIMARY OR A SECONDARY ALCOHOL REACTS FASTER IN THIS ACYLATION [J].

NAEMURA, K ;

FUKUDA, R ;

KONISHI, M ;

HIROSE, K ;

TOBE, Y .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1994, (10) :1253-1256

[10] ENANTIOSELECTIVE TRANSESTERIFICATIONS OF 2-METHYL-1-ALCOHOLS CATALYZED BY LIPASES FROM PSEUDOMONAS [J].

NORDIN, O ;

HEDENSTROM, E ;

HOGBERG, HE .

TETRAHEDRON-ASYMMETRY, 1994, 5 (05) :785-788

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