STRATEGIES FOR THE SYNTHESIS OF C-DISACCHARIDES CONTAINING D-SUGAR AND L-SUGAR

被引:34
作者
ARMSTRONG, RW
SUTHERLIN, DP
机构
[1] Department of Chemistry and Biochemistry, University of California at Los Angeles, Los Angeles
关键词
D O I
10.1016/0040-4039(94)80107-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The osmylation of C-1 homologated diene ester monosaccharides readily affords C-disaccharides of diverse but predictable stereochemistry. As an example, D-glu-alpha(1,6)-D-gal (3), D-glu-alpha(1,6)-L-gal (4), D-glu-alpha(1,6)-D-ido (10), and D-glu-alpha(1,6)-L-ido (11) were synthesized from a single precursor.
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页码:7743 / 7746
页数:4
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