ORGANOMETALLIC CHEMISTRY OF DIPHOSPHAZANES .8. SYNTHESIS, SPECTROSCOPIC STUDIES AND CRYSTAL-STRUCTURE OF FAC-[MO(CO)3(MECN)(PH2PN(IPR)P(PH)(DMP))], AND ITS REACTIONS WITH TERTIARY PHOSPHINES

被引：20

作者：

BABU, RPK ^{[1
]}

KRISHNAMURTHY, SS ^{[1
]}

NETHAJI, M ^{[1
]}

机构：

[1] INDIAN INST SCI,DEPT INORGAN & PHYS CHEM,BANGALORE 560012,KARNATAKA,INDIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 454卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83236-O

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of fac-[Mo(CO)3(MeCN)3] with the unsymmetrical diphosphazane Ph2PN(iPr)P(Ph)(DMP) (L) gives the complex fac-[Mo(CO)3(MeCN)(L)] (2) in almost quantitative yield. The structure of the complex has been determined by an X-ray diffraction study. The compound reacts with PR3 (where R = Ph, OPh) to give fac-[Mo(CO)3(PR3)(L)] (3a, 4a), which undergoes an intramolecular isomerization to afford mer-[Mo(CO)3(PR3)(L)] (3b, 4b). Synthesis of cis-[Mo(CO)4(L)] (1) and fac-[MO(CO)3L] (2a) and their spectroscopic data are also reported.

引用

页码：157 / 163

页数：7

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