SYNTHESES AND CHARACTERIZATIONS OF TIN COMPLEXES OF METHYLENEDIPHENYLPHOSPHINATE LIGANDS - THE CRYSTAL-STRUCTURES OF [PH4-XSN(CH2P(S)PH2)X] (X=1-4) AND [PH2SNCL(CH2P(O)PH2)2)]2

被引：7

作者：

FACKLER, JP ^{[1
]}

GARZON, G ^{[1
]}

KRESINSKI, RA ^{[1
]}

MURRAY, HH ^{[1
]}

RAPTIS, RG ^{[1
]}

机构：

[1] TEXAS A&M UNIV,MOLEC STRUCT & BONDING LAB,COLLEGE STN,TX 77843

来源：

POLYHEDRON | 1994年 / 13卷 / 11期

关键词：

D O I：

10.1016/S0277-5387(00)80101-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions between methylenediphenylphosphinate anions [CH2P(E)Ph2]-(E = S, O) and appropriate chlorophenyltin(IV) compounds in tetrahydrofuran afforded the organotin compounds [Ph4-xSn(CH2P(S)Ph2)x], (x = 1-4), 1-4 and [Ph2SnCl(CH2 P(O)Ph2)]2, 5. All compounds have been characterized structurally, 1-4 as 4-coordinate monometallic species and 5 as a bimetallic 8-membered metallacycle which is 5-coordinate at each metal atom.

引用

页码：1705 / 1713

页数：9

共 24 条

[1] ACETATES AND ACETATO-COMPLEXES .3. CRYSTAL AND MOLECULAR-STRUCTURE OF TETRAMETHYLAMMONIUM PENTA-ACETATOSTANNATE(IV) [J].

ALCOCK, NW ;

TRACY, VL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (21) :2246-2249

[2]

DAVIES AG, 1972, COMPREHENSIVE ORGANO, V2

[3] POLYMERIC MERCURY COMPLEXES WITH ONE-DIMENSIONAL CHAIN STRUCTURES .2. SYNTHESIS AND CRYSTAL-STRUCTURE OF [(HG(CH2P(O)PH2)2)2BRLI]N [J].

FACKLER, JP ;

KRESINSKI, RA .

ORGANOMETALLICS, 1991, 10 (09) :3392-3395

[4] STRUCTURE OF DIAQUADIBROMOBIS(TETRAHYDROFURAN)DILITHIUM TETRAKIS(METHYLENEOXYDIPHENYLPHOSPHINATO)DIMERCURY(II), [HG(BR)(CH2P(O)PH2)2LI(H2O)(C4H8O)]2 [J].

KRESINSKI, RA ;

FACKLER, JP .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 :1059-1061

[5] ISOMERIC SPECIES OF [AUCH2P(S)(C6H5)2I]2 - MIXED-VALENT AU(I)-AU(III) AND ISOVALENT AU(II)-AU(II) COMPLEXES WITH THE SAME METHYLENETHIOPHOSPHINATE LIGAND [J].

MAZANY, AM ;

FACKLER, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (03) :801-802

[6] SYNTHESIS AND CHARACTERIZATION OF AN EXCEPTIONALLY AIR-STABLE ORGANO-METALLIC NICKEL(II) COMPLEX OF THE ORGANO-LITHIUM REAGENT (C6H5)2P(S)CH2LI - THE X-RAY CRYSTAL-STRUCTURE OF CHLORO(TRIPHENYLPHOSPHINE)[DIPHENYL(METHYLENE)-PHOSPHORANYLTHIO-S,C]NICKEL(II), NICH2P(S)PH2(PPH3)CL [J].

MAZANY, AM ;

FACKLER, JP .

ORGANOMETALLICS, 1982, 1 (05) :752-753

[7] STRUCTURAL CHARACTERIZATION OF A LINEAR [AU=PT=AU] COMPLEX, AU2PT(CH2P(S)PH2)4, AND ITS OXIDIZED LINEAR METAL-METAL BONDED [AU-PT-AU] PRODUCT, AU2PT(CH2P(S)PH2)4CL2 [J].

MURRAY, HH ;

BRIGGS, DA ;

GARZON, G ;

RAPTIS, RG ;

PORTER, LC ;

FACKLER, JP .

ORGANOMETALLICS, 1987, 6 (09) :1992-1995

[8] SULFUR-CONTAINING GOLD(III) CHELATES AND THEIR USE IN HETEROVALENT DIMER SYNTHESIS - CRYSTAL-STRUCTURES OF AUIII[CH2P(S)PH2]2BR,[AUIII[S2P(OH)PH]2]CL, AND AUIII[CH2P(S)PH2][S2CN(ET)2]2 [J].

MURRAY, HH ;

GARZON, G ;

RAPTIS, RG ;

MAZANY, AM ;

PORTER, LC ;

FACKLER, JP .

INORGANIC CHEMISTRY, 1988, 27 (05) :836-842

[9] OXY AND THIO PHOSPHORUS-ACID DERIVATIVES OF TIN .14. X-RAY CRYSTAL AND MOLECULAR-STRUCTURE OF THE DIMERIC BIS[BIS(O,O'-DIPHENYL THIOPHOSPHATO)DIPHENYLTIN(IV) HYDROXIDE], [HO(C6H5)2SNOP(S)(OC6H5)2]2, AT 138-K [J].

NASSER, FAK ;

HOSSAIN, MB ;

VANDERHELM, D ;

ZUCKERMAN, JJ .

INORGANIC CHEMISTRY, 1983, 22 (21) :3107-3111

[10]

NG SW, 1989, J ORGANOMET CHEM, V377, P211

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