共 23 条
TEMPORAL EVOLUTION IN UV-LASER-INDUCED DEPOSITION FROM MO(CO)6
被引:8
作者:
ALEXANDRESCU, R
ANDREI, A
MORJAN, I
MULENKO, S
STOICA, M
VOICU, I
机构:
[1] INST NUCL RES,PITESTI,ROMANIA
[2] KIEV MET PHYS INST,KIEV,UKRAINE,USSR
关键词:
D O I:
10.1016/0040-6090(92)90905-Q
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
The temporal evolution of the composition of films obtained by laser photolysis at 248 nm was studied. As the number of laser pulses increases (800-7000 pulses at 10 Hz), the C:Mo ratio and the deposition rate decrease, while the presence of high oxidation states is revealed by X-ray photoelectron spectroscopy analysis of molybdenum and carbon chemical states. The mechanism of photodecomposition indicates more complex gas phase processes than those initiated by single-photon dissociation of the carbonyl.
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页码:68 / 74
页数:7
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