THE BENZANNELATION APPROACH TO NOVEL GALLIUM AND INDIUM HETEROCYCLES

被引：19

作者：

DECKEN, A ^{[1
]}

GABBAI, FP ^{[1
]}

COWLEY, AH ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT CHEM & BIOCHEM,AUSTIN,TX 78712

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 15期

关键词：

D O I：

10.1021/ic00119a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first gallafluorene (1) has been prepared by two routes: (i) the reaction of Ar*GaC1(2) (Ar* = 2,4,6-t-Bu(3)C(6)H(2)) With 2,2'-dilithiobiphenyl (2), and (ii) the reaction of 2 with GaC1(3) followed by treatment with Ar*Li. The analogous indafluorene (4) has been prepared via the reaction of Ar*InBr2 with 2 . 2TMEDA. The structure of 1 has been determined by X-ray crystallography.

引用

页码：3853 / 3854

页数：2

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