SYNTHESIS AND STRUCTURE OF [(CH2)(4)GA-MU-AS(T)BU(2)](2) - THE FIRST EXAMPLE OF A GALLACYCLOPENTANE

被引：7

作者：

COWLEY, AH

CORBELIN, S

JONES, RA

LAGOW, RJ

NAIL, JW

机构：

[1] Department of Chemistry, Biochemistry The University of Texas at Austin, Austin

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 464卷 / 01期

关键词：

GALLIUM; ARSENIC; CYCLOPENTANE; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(94)87019-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first gallacyclopentane, [(CH2)(4)Ga-mu-As(t)Bu(2)](2) (4) has been synthesized in 61% yield by treatment of Li(CH2)(4)Li with C1(2)GaAs(t)Bu(2) in Et(2)O solution. The structure of 4 has been established by X-ray crystallography: monoclinic, space group I 2/m (No. 12) with a=8.624(6), b=11.389(12), c=14.921(13) Angstrom, beta= 95.330(10)degrees, and Z=4 (monomeric units).

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页码：C1 / C3

页数：3

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