MIXED ALKYL DIALKYLTHIOCARBAMATES OF ZINC AND CADMIUM - POTENTIAL PRECURSORS FOR II/VI MATERIALS - X-RAY CRYSTAL-STRUCTURE OF [MEZNS2CNET2]2

被引：65

作者：

HURSTHOUSE, MB

MALIK, MA

MOTEVALLI, M

OBRIEN, P

机构：

[1] Department of Chemistry, Queen Mary and Westfield College, London Et 4NS, Mile End Road

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 03期

关键词：

D O I：

10.1021/om00049a036

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Compounds with the formula RMS2CNR'2 (R or R' = Me or Et, M = Zn; R = Me, R' = Et, M = Cd) have been synthesized and characterized. An X-ray crystal structure for MeZnS2CNEt2 has been determined and shows the complex to be dimeric. The compound crystallizes in space group P2(1)/c, a = 6.776 (1) angstrom, b = 10.341 (4) angstrom, and c = 10.341 (4) angstrom, alpha = 90-degrees, beta = 97.3 (3)-degrees, and gamma = 90-degrees. The zinc complexes may be useful precursors for the deposition of ZnS.

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页码：730 / 732

页数：3

相关论文

共 28 条

[1] DIMETHYL INDIUM DITERTIARY BUTYL PHOSPHINE - A NOVEL PRECURSOR FOR THE GROWTH OF INDIUM-PHOSPHIDE BY METAL ORGANIC MOLECULAR-BEAM EPITAXY [J].

ANDREWS, DA ;

DAVIES, GJ ;

BRADLEY, DC ;

FAKTOR, MM ;

FRIGO, DM ;

WHITE, EAD .

SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 1988, 3 (10) :1053-1056

[2]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[3] TRIMETHYLGALLIUM .V. REACTIONS OF TRIMETHYL-ALUMINIUM -GALLIUM AND -INDIUM WITH SOME PRIMARY AND SECONDARY PHOSPHINES AND ARSINES [J].

BEACHLEY, OT ;

COATES, GE .

JOURNAL OF THE CHEMICAL SOCIETY, 1965, (MAY) :3241-&

[4] FACTORS AFFECTING THE DEGREE OF ASSOCIATION OF ALKYL-ZINC AND HYDRIDO-ZINC COMPOUNDS [J].

BELL, NA ;

MOSELEY, PT .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 325 (1-2) :47-53

[5] POTENTIAL PRECURSORS TO ELECTRONIC MATERIALS - 3-COORDINATE CD IN [MECD(MU-TERT-BU2P)]3, THE 1ST CADMIUM DIORGANOPHOSPHIDE [J].

BENAC, BL ;

COWLEY, AH ;

JONES, RA ;

NUNN, CM ;

WRIGHT, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (13) :4986-4988

[6] SYNTHESIS, STRUCTURE, AND GAS-PHASE DECOMPOSITION OF [CD(SC6H2TBU3)2]2 [CD(SEC6H2TBU3)2]2 - 1ST EXAMPLES OF LOW-COORDINATE VOLATILE CADMIUM CHALCOGENOLATO COMPLEXES [J].

BOCHMANN, M ;

WEBB, K ;

HARMAN, M ;

HURSTHOUSE, MB .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (06) :638-639

[7] STRUCTURAL STUDIES OF METAL DITHIOCARBAMATES .3. CRYSTAL AND MOLECULAR STRUCTURE OF ZINC DIETHYLDITHIOCARBAMATE [J].

BONAMICO, M ;

MAZZONE, G ;

VACIAGO, A ;

ZAMBONEL.L .

ACTA CRYSTALLOGRAPHICA, 1965, 19 :898-&

[8] THE PREPARATION OF LARGE SEMICONDUCTOR CLUSTERS VIA THE PYROLYSIS OF A MOLECULAR PRECURSOR [J].

BRENNAN, JG ;

SIEGRIST, T ;

CARROLL, PJ ;

STUCZYNSKI, SM ;

BRUS, LE ;

STEIGERWALD, ML .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (11) :4141-4143

[9] METALORGANIC CHEMICAL VAPOR-DEPOSITION OF WIDE BAND-GAP II-VI-COMPOUNDS [J].

COCKAYNE, B ;

WRIGHT, PJ .

JOURNAL OF CRYSTAL GROWTH, 1984, 68 (01) :223-230

[10] SINGLE-SOURCE III/V PRECURSORS - A NEW APPROACH TO GALLIUM-ARSENIDE AND RELATED SEMICONDUCTORS [J].

COWLEY, AH ;

JONES, RA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (09) :1208-1215