We studied the relationship between the growth conditions, the nitrogen profile, and the charge to breakdown of N2O oxynitrides grown in a RTP and in a conventional furnace. RTP oxynitride shows nitrogen accumulation at the Si/SiO2 interface. On the other hand, furnace oxynitride shows almost uniform nitrogen distribution in the bulk, resulting in poor charge to breakdown characteristics. We find that two-step oxynitridation processes provide nitrogen accumulation at the Si/SiO2 interface and result in better electrical properties than those of one-step oxynitrides.