MONOCYCLOOCTATETRAENYL(THIOLATO)SAMARIUM(III) COMPLEXES FROM THE REACTION OF METALLIC SAMARIUM WITH CYCLOOCTATETRAENE AND DIARYLDISULFIDE - CRYSTAL-STRUCTURES OF [SM(MU-SPH)(C8H8)(THF)2]2 AND [(SM[MU-S(2,4,6-TRIISOPROPYLPHENYL)](C8H8)(THF))2]

被引：48

作者：

MASHIMA, K

NAKAYAMA, Y

KANEHISA, N

KAI, Y

NAKAMURA, A

机构：

[1] OSAKA UNIV,FAC SCI,DEPT MACROMOLEC SCI,TOYONAKA,OSAKA 560,JAPAN

[2] OSAKA UNIV,FAC SCI,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 24期

关键词：

D O I：

10.1039/c39930001847

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metallic samarium reacts directly with cyclooctatetraene in the presence of diaryldisulfide to give cyclooctatetraenyl(thiolato)samarium(III) complexes, [Sm(mu-SAr)(C8H8)(thf)n]2 (thf = tetrahydrofuran) (1, Ar = C6H5, n = 2; 2, Ar = 2,4,6-Me3-C6H2, n = 2; 3, Ar = 2,4,6-(Pri)3-C6H2, n = 1), the structures of which are confirmed by single crystal X-ray analyses of 1 and 3, while Yb reacts with diphenyldisulfide in thf to afford [Yb(SPh)2(thf)]n.

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页码：1847 / 1848

页数：2

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